
The boiling point of a liquid depends on several factors, including the type of liquid, atmospheric pressure, surface area of the liquid, temperature of the liquid and air, humidity, and wind speed. Alcohol has a lower boiling point than water due to its chemical composition, specifically its polarity and hydrogen bonding with water. The boiling point of ethanol, the type of alcohol found in drinks, is approximately 78°C, while the boiling point of water is 100°C. This difference in boiling points can be utilised to separate the two liquids through a process called distillation, where a liquid is carefully heated to boil off more volatile compounds.
| Characteristics | Values |
|---|---|
| Boiling point of ethanol | 78.37°C or 173.1°F |
| Boiling point of water | 212°F or 100°C |
| Boiling point of methanol | 66°C or 151°F |
| Boiling point of isopropyl alcohol | 80.3°C or 177°F |
| Flash point of ethanol | 13°C |
| Factors affecting boiling point | Salt, sugar, atmospheric pressure, number of carbon atoms, polarity, hydrogen bonding with water |
| Vapour pressure | Higher in alcohol than water |
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What You'll Learn

Ethanol's boiling point is approximately 78°C
Ethanol, the type of alcohol found in drinks, has a boiling point of approximately 78°C (78.37°C or 173.1°F to be precise). This is notably lower than the boiling point of water, which is 100°C. The reason for this difference lies in the chemical structure of ethanol, which contains an oxygen-hydrogen (OH) bond. This bond results in ethanol being a polar molecule with opposite charges on its ends. This polarity, along with hydrogen bonding between ethanol and water, contributes to its lower boiling point compared to water.
The boiling point of a substance is influenced by various factors, including atmospheric pressure and the presence of other substances. For example, adding salt or sugar to an ethanol-water mixture can alter its boiling point. Salt increases the boiling point, whereas sugar lowers it. This occurs because salt and sugar affect the number of water molecules in the solution, which in turn impacts the ease of vapour escape. Additionally, the rate of evaporation, which is related to boiling, depends on factors such as surface area, temperature, humidity, and wind speed.
The unique properties of ethanol, including its lower boiling point compared to water, have practical implications. One example is the use of distillation to separate ethanol from water and other liquids. Distillation involves carefully heating a liquid to vaporize more volatile compounds, allowing for their separation. However, it is important to note that distillation cannot completely separate ethanol and water due to their tendency to form an azeotrope, where they bind together strongly.
The boiling point of ethanol is also relevant to its flammability. Ethanol has a low flash point of around 13°C, which is the lowest temperature at which it can form a flammable vapour. This means that ethanol can ignite even when it is not boiling, but the combustion depends on factors such as concentration, oxygen levels, and the presence of a spark or flame.
In summary, ethanol's boiling point of approximately 78°C is a result of its chemical structure and polarity. This relatively low boiling point has implications for both practical applications, such as distillation, and safety considerations due to its flammability. Understanding the factors that influence the boiling point of substances like ethanol is crucial in various scientific and industrial contexts.
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Atmospheric pressure affects the boiling point
The boiling point of a liquid is influenced by the atmospheric pressure acting on it. Atmospheric pressure is the pressure exerted by the weight of air molecules above the liquid's surface. When the atmospheric pressure is high, the boiling point of the liquid increases. Conversely, when the atmospheric pressure decreases, the liquid's boiling point also drops. This relationship between atmospheric pressure and boiling point is observed until the critical point is reached, beyond which an increase in pressure will no longer raise the boiling point.
The boiling point of ethanol, the type of alcohol commonly found in beverages, is approximately 78°C at atmospheric pressure. However, the boiling point can vary depending on altitude or elevation, which influences atmospheric pressure. For example, water boils at 100°C at sea level, but at an altitude of 1,905 meters, its boiling point drops to 93.4°C due to the lower atmospheric pressure at that height.
The boiling point of ethanol can also be altered by adding substances like salt or sugar to an ethanol-water mixture. Salt increases the boiling point, whereas sugar lowers it. This occurs because salt and sugar affect the number of water molecules in the solution, which in turn impacts the ease with which vapour can escape.
The rate of evaporation, which is closely related to boiling, depends on factors such as surface area, temperature, humidity, and wind speed. Evaporation can occur at temperatures below the boiling point, as it only requires the escape of surface molecules, whereas boiling involves the escape of molecules from anywhere within the liquid.
In summary, atmospheric pressure has a direct effect on the boiling point of liquids, including alcohol. The specific type of alcohol, the presence of additional substances, and environmental factors like altitude, also influence the boiling point. These factors collectively determine the temperature at which a liquid boils.
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Salt and sugar change alcohol's boiling point
The boiling point of ethanol, the type of alcohol found in drinks, is approximately 78°C. This is lower than the boiling point of water, which is 100°C. The boiling point of ethanol can change depending on other factors, too. For example, adding salt or sugar to an ethanol and water mixture can change its boiling point. Salt increases the boiling point of ethanol, while sugar lowers it.
Salt and sugar affect the boiling point of ethanol by changing the number of water molecules in the solution. The more vapour there is, the easier it is to boil. The less vapour there is, the harder it is to boil. Salt and sugar change the number of water molecules in the solution, which affects how easily they can escape as vapour.
The boiling point of ethanol also depends on the number of carbon atoms in a molecule. As the number of carbon atoms increases, the boiling point of ethanol also increases. Additionally, the boiling point of ethanol can be affected by atmospheric pressure. The boiling point decreases as atmospheric pressure decreases, so it will be slightly lower than published values unless you are at sea level.
It's important to note that ethanol has a lower flash point than its boiling point. The flash point is the lowest temperature at which ethanol can form a flammable vapour, which is around 13°C for ethanol. This means that ethanol can ignite at temperatures below its boiling point, but combustion also depends on factors such as concentration, oxygen levels, and heat.
Distillation can be used to separate ethanol from water, as they have different boiling points. However, it is difficult to completely separate the two chemicals due to their azeotropic properties. The highest retention of alcohol in cooking occurs when alcohol is added to a boiling liquid and then removed from the heat, resulting in about 85% of the alcohol remaining.
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Alcohol and water form an azeotrope
The azeotropic behaviour arises from the concentration-dependence of the surface composition. While ethanol dominates the surface, water is almost entirely depleted from the surface for most mixing ratios. The different intermolecular bonding patterns of the two components cause water to penetrate the surface. The addition of surface water increases its relative vapour pressure, further contributing to the azeotropic behaviour.
The ethanol-water azeotrope can be purified to obtain 100% pure ethanol. This can be achieved by shaking the liquid with calcium oxide, which reacts strongly with water to form the non-volatile compound, calcium hydroxide. The calcium hydroxide can then be separated by filtration, and the filtrate redistilled to obtain pure ethanol.
It is important to note that not all azeotropes fall into the positive or negative categories. Some complex azeotropes, such as the ternary azeotrope formed by acetone, chloroform, and methanol, have boiling points that fall between the boiling points of their constituents. These azeotropes are neither positive nor negative and are known as saddle azeotropes.
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Different types of alcohol have different boiling points
The boiling point of alcohol depends on the type of alcohol being used, as well as the atmospheric pressure. The boiling point decreases as the atmospheric pressure decreases, so it will be slightly lower than published values unless you are at sea level.
For example, ethanol, the type found in alcoholic drinks, has a boiling point of around 78°C due to its polarity and hydrogen bonding with water. However, the boiling point of ethanol can be altered by adding salt or sugar. Salt increases the boiling point, while sugar lowers it. This is because they affect the number of water molecules in the solution.
Other types of alcohol have different boiling points. For instance, methanol (methyl alcohol, wood alcohol) has a boiling point of 66°C or 151°F, while isopropyl alcohol (isopropanol) boils at 80.3°C or 177°F.
The higher boiling points of alcohols compared to alkanes with similar molecular weights can be attributed to the presence of the OH group, which allows alcohol molecules to engage in hydrogen bonding. This results in stronger intermolecular forces and higher boiling points.
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Frequently asked questions
Alcohol has a lower boiling point than water due to its chemical structure. Ethanol, the type of alcohol found in drinks, has a boiling point of around 78°C, whereas water boils at 100°C.
The boiling point of alcohol depends on the specific type of alcohol and the atmospheric pressure. Different types of alcohol have varying boiling points, for example, methanol boils at 66°C, while isopropyl alcohol boils at 80.3°C. The boiling point of alcohol also decreases as atmospheric pressure decreases.
Adding salt or sugar to an ethanol and water mixture can alter its boiling point. Salt increases the boiling point, while sugar lowers it. This occurs because these substances change the number of water molecules in the solution, affecting the ease of vapour escape.
Alcohol and water form an azeotrope, a type of chemical bond, which makes it challenging to separate them using heat. While distillation can be employed to separate the two liquids to some extent, it cannot entirely divide them due to this azeotropic relationship.











































