
Breathalyzers are devices that measure a person's alcohol concentration through a breath sample. They are commonly used by law enforcement to determine whether a person has been drinking and driving. The alcohol detected by the breathalyzer comes from the airways of the lungs, and not from the alveoli. The breathalyzer calculates the concentration of alcohol in the breath to determine whether a person has consumed too much alcohol to drive safely. The breath sample is assumed to come from the lungs, but alcohol may also come from the mouth, throat, or stomach. Breathalyzers can detect alcohol for up to 24 hours, but this varies between individuals.
| Characteristics | Values |
|---|---|
| What does a breathalyzer measure? | The amount of alcohol in the air a person breathes out |
| How does it work? | It measures the percentage of alcohol in a person's blood |
| What happens when a person consumes alcohol? | The body absorbs alcohol through the stomach lining into the bloodstream. As blood passes through the lungs, some alcohol evaporates and moves into the lungs. |
| How does the concentration of alcohol in the lungs relate to the concentration in the blood? | The ratio of breath alcohol to blood alcohol is roughly 2,100:1. |
| How does the breathalyzer calculate the BAC? | It uses a partition ratio to determine the BAC almost instantly from the air a person exhales. |
| What is the BAC limit in the US? | 0.08%, but in Utah, the limit is 0.05%. |
| What are the other ways to measure BAC? | Blood, saliva, urine, or hair analyses |
| How long can a breathalyzer detect alcohol? | Up to 24 hours, but this varies between individuals |
| What factors affect the detection time? | Metabolism of alcohol, weight, age, and gender |
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What You'll Learn

Alcohol vapour in breath
A breathalyzer is a device that measures a person's alcohol concentration through a breath sample. It is commonly used by law enforcement officers during traffic stops to determine whether a person has consumed too much alcohol to drive safely. The breathalyzer calculates the concentration of alcohol in the breath, which reflects the percentage of alcohol in a person's blood.
The alcohol vapour in a person's breath comes from the airways of the lungs, and not from the alveoli. During breathing, the inspired air picks up water and alcohol from the airways. Almost all uptake occurs in the upper airways, so the BrAC is most affected by the alcohol concentration in the bronchial circulation, which supplies blood to these airways. When the air reaches the alveoli, it is already near equilibrium, which is why inhaling dry air does not dry out the lungs significantly.
The alcohol vapour in breath can be detected by breathalyzers for up to 24 hours, although this timeframe varies depending on the individual and the quantity of alcohol consumed. The detection time is influenced by a person's metabolism of alcohol, which is affected by factors such as weight, age, and gender. Generally, older individuals and females metabolize alcohol more slowly, leading to a longer detection time in the breath.
The presence of alcohol vapour in the breath is determined through a chemical reaction in the breathalyzer. The alcohol vapour reacts with an orange solution of potassium dichromate, turning it green. This colour change creates an electrical current, which the breathalyzer converts into a value to determine the BAC. The degree of colour change is directly related to the level of alcohol in the exhaled breath.
While breathalyzers are useful tools for estimating blood alcohol content, they may not always provide accurate results. Factors such as mouth alcohol, recent use of mouthwash or breath fresheners, and interfering substances can skew the readings. Additionally, individuals with higher-than-normal levels of acetone in their breath may have it detected as ethanol, leading to false positives.
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Mouth alcohol
A breathalyzer is a device that measures the alcohol content in a person's breath, known as BrAC (breath alcohol content). It is used to estimate the person's BAC (blood alcohol content).
However, the breath test can be affected by alcohol in the defendant’s mouth, known as 'mouth alcohol'. Mouth alcohol can cause improperly high BAC test results. It is the most common cause of falsely high BrAC. Even a tiny amount of mouth alcohol can significantly impact the breath-alcohol reading.
There are several ways in which mouth alcohol can be generated. Alcohol can be trapped in dental pits or cavities, particularly in those who have recently had dental surgery or suffer from dental conditions. Periodontal disease can also create pockets in the gums that will contain alcohol for longer periods. Recent use of mouthwash or breath fresheners can also skew results upwards, as they can contain high levels of alcohol. For example, Listerine mouthwash contains 26.9% alcohol and can affect results for between 5 and 10 minutes. Kissing an intoxicated person can also produce false results due to residual alcohol in the mouth.
To guard against mouth-alcohol contamination, certified breath-test operators and police officers are trained to observe a test subject for at least 15–20 minutes before administering the breath test. During this time, the subject must not eat, drink, burp, regurgitate, or do anything else that would cause the presence of mouth alcohol.
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Blood alcohol content (BAC)
A breathalyzer is a device that measures a person's blood alcohol content (BAC) by analyzing their breath. It estimates the amount of alcohol in the blood based on the ethanol content in the breath. The breathalyzer assumes that the alcohol in the breath sample comes from the lungs, but it can also originate from the mouth, throat, or stomach, leading to inaccurate readings.
When a person consumes alcohol, it is absorbed through the stomach lining into the bloodstream. As blood circulates through the body, it passes through the lungs, where some alcohol evaporates into the airways. This alcohol acts similarly to water vapour and is exhaled when we breathe. The concentration of alcohol in the lungs is proportional to the concentration in the blood, allowing breathalyzers to estimate BAC.
The breathalyzer test typically requires individuals to blow into a device called a breath analyzer. The breath sample is then analyzed to determine the BAC level. The device calculates the concentration of alcohol in the breath to assess whether an individual is fit to perform tasks such as driving.
While breathalyzers are commonly used by law enforcement, single-use and personal breathalyzers are also available to the general public. These devices can help individuals determine if they are too intoxicated to drive. However, it is important to note that the accuracy of personal breathalyzers may vary, and they might not always be sensitive enough to accurately capture blood alcohol levels.
The detection window of a breathalyzer can vary between individuals, typically ranging from 12 to 24 hours. Factors such as metabolism, weight, age, and gender influence how long alcohol can be detected in the breath. Additionally, certain substances and interfering agents can impact the accuracy of breathalyzer readings.
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Chemical reaction
A breathalyzer is a device that measures a person's blood alcohol content (BAC) by analyzing their breath. The breathalyzer test is based on the discovery that small amounts of alcohol are excreted in the breath. When a person consumes alcohol, it is absorbed through the stomach lining into the bloodstream. As blood passes through the lungs, some alcohol evaporates and moves into the airways of the lungs. This alcohol acts similarly to water vapour and is exhaled when a person breathes.
The breathalyzer test assumes that the alcohol in the breath sample comes from the lungs. However, alcohol may also come from the mouth, throat, or stomach, leading to false positives. To prevent this, certified breath-test operators and police officers are trained to observe the test subject for 15-20 minutes before administering the test. Some breathalyzers also have built-in safeguards to detect mouth alcohol.
The breathalyzer device typically consists of a mouthpiece and two chambers filled with a red-orange solution of potassium dichromate and other chemicals. When a person exhales into the mouthpiece, the alcohol vapour in their breath reacts with the potassium dichromate solution, causing it to turn green. This colour change creates an electrical current, which the breathalyzer converts into a numerical value for the BAC. The degree of colour change is directly related to the level of alcohol in the person's breath.
The breathalyzer test is widely used by law enforcement to determine whether individuals are fit to drive. The legal BAC limit in most states is 0.08%, but it can vary between states and countries. It is important to note that the accuracy of breathalyzers can vary depending on the type of test and individual factors such as metabolism, weight, and age. Other tests, such as blood, urine, or hair analyses, can also be used to confirm BAC levels.
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Accuracy
The accuracy of breathalyzers depends on various factors, including the type of test used, the individual's metabolism, and the presence of interfering substances. While breathalyzers are widely used to estimate blood alcohol content (BAC), they do not directly measure BAC and are subject to certain limitations.
Breathalyzers estimate BAC by measuring the concentration of alcohol in an individual's breath, known as breath alcohol content (BrAC). The assumption is that the alcohol in the breath sample comes from the lungs, where alcohol evaporates from the blood during respiration. However, alcohol may also originate from the mouth, throat, or stomach, leading to inaccurate readings. For example, recent use of mouthwash or breath fresheners containing alcohol can skew results upward. To mitigate this issue, certified breath-test operators and police officers are trained to observe the test subject for at least 15–20 minutes before administering the test.
The accuracy of breathalyzers can vary depending on the specific device and the individual using it. A 2014 study found that some personal-use breathalyzers were not sufficiently sensitive to determine if it was safe to drive after consuming alcohol. User error can also affect the accuracy of at-home BAC tests. While most alcohol breath tests sold to the public have an accuracy of 90% or higher, one study reported a device with an accuracy as low as 26%. Even a small margin of error can have significant consequences, potentially leading to impaired drivers on the road.
Additionally, breathalyzers may not always be sensitive enough to accurately capture blood alcohol levels. Other factors, such as an individual's weight, age, and gender, can influence their metabolism of alcohol, affecting how long alcohol remains detectable in their breath. For example, older individuals and females generally metabolize alcohol more slowly, resulting in longer detection times.
Furthermore, breathalyzers can be susceptible to interference from certain substances. For instance, individuals with higher-than-normal levels of acetone in their breath, such as diabetics or those on specific diets, may have it detected as ethanol by the breathalyzer. Other substances, such as activated charcoal, oxidizing gases, or organic interferents, can also produce false readings by absorbing or mimicking alcohol vapour.
To ensure accuracy, evidential breath testing in police stations typically employs fuel cell or infrared cell technology. Fuel cell devices convert the chemical energy released during oxidation into an electrical voltage, with higher voltages indicating a greater alcohol presence. Infrared cell devices direct infrared energy through the sample, measuring the amount of energy absorbed by ethanol. These methods provide more accurate readings by continuously monitoring the expired air and ensuring deep lung air (alveolar air) is sampled.
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Frequently asked questions
The alcohol detected by a breathalyzer comes from the airways of the lungs, not the alveoli. The breathalyzer calculates the concentration of alcohol in the breath to determine whether a person has consumed too much alcohol to drive safely.
A breathalyzer measures the amount of alcohol, or ethanol, in a person's system. It does this by measuring the person's breath alcohol content (BrAC). The breath sample is assumed to come from the lungs, but it may also come from the mouth, throat, or stomach. The breath analyzer's internal computer calculates the concentration of alcohol in the breath to estimate the person's blood alcohol content (BAC).
The length of time a breathalyzer can detect alcohol depends on the individual. In some cases, a breathalyzer may detect alcohol for up to 12 hours, while in other cases, it may work for twice that long, or up to 24 hours. Older individuals and females tend to metabolize alcohol more slowly, so alcohol may stay in their breath for longer.










































